Yes, I have done this and it is pretty cool. It can generate a very fine finish like #2RMS 35 minutes for 1" area)
some things to consider though.
1. you need a electrode for every shape and each detail that is EDM'd.
For the very fine detail mirror or A finishes, each electrode needs to have a mirror finish, that requires additional time just in trode making. For the very fine detail better graphite is a necessity, Poco AF series is absolutly needed.
2 This type of machine is specialized Mits and Makino both have this technology but they cost 150k plus the additive is relatively short lived and costly to maintain. I believe that they make way more money burning in the B type finishes (10 +- minutes per 1" area with just a basic electrode non directional finish) or just standard finishes that require no trode polish.
3. Every EDM creates a hard surface called recast, yep lots of arguments here but it is there to some degree. These machines do have a very fine recast layer. Every surface that needs manual polish should have a vapor or bead blast. A very low pressure with fine grit will not harm corners but removes this, you will not believe how nice your polishing will go after this.
4. A good polisher still may be required. After all the trode polishing and care in handling of those precious trodes, you will find that not all of the detail will be perfect and those areas, small they may be, still can be molding issues.