Not only is the square not square, but it also has a small glitch on the bottom left corner where two of the side lines overlap.
Best advice is to start again, use the "square" tool to draw the square, rather than use single lines. Draw the whole lot the finnished size first, then use the offset tool (edit -> offset) with an offset the radius of the cutter you will use, to offset each entity to allow for the cutter. Next job is to explode the square into lines (format -> explode) then save as DXF R14 (use "setup" once you have selected DXF from the save-as dialogue box).
Don't mean to offend you by talking you through each step, but you said you were new to CAD. Hope this helps!
(Note: The opinions expressed in this post are my own and are not necessarily those of CNCzone and its management)