If you want to set the work offsets without using G10 the variable numbers for the standard 6 generally are.
I do not remember any machine/control where they are at a different location.
The extended offsets and tool offsets are not as well defined.
Code:
X axis Y axis Z axis 4th etc.
G54 #5221 #5222 #5223 #5224
G55 #5241 #5242 #5243 #5244
G56 #5261 #5262 #5263 #5264
G57 #5281 #5282 #5283 #5284
G58 #5301 #5302 #5303 #5304
G59 #5321 #5322 #5323 #5324
EXT #5201 #5202 #5203 #5204
The EXT work offset is basically added to the values in the normal work offsets. So if you put a 1.0 in #5201 you move all the work offsets 1 inch in the X axis.