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IndustryArena Forum > Community Club House > Environmental / Alternate Energy > Biogas IE: methane from organic matter
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  1. #1
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    Biogas IE: methane from organic matter

    Harold Bate back in the 70s was using methane generated from pig and chicken manure mixed with straw to power his car in Great Britain.
    http://journeytoforever.org/biofuel_...hane_bate.html

    I mention this as an alternative energy not because I believe it would be good for everyone but more secluded people and/or farmers with alot of animals or "organic wastes" could be generating power (and some do already). The sludge that is left over after bio-digestion is said to be a good fertilizer.

    I have a few questions about what "organic wastes" can be used in a bio-digester...

    Can the mash left over from the production of alcohol be used as "charge" for a methane plant? Essentially by growing the grain to make alcohol then using the mash to produce methane and fertilizer your getting 2 kinds of fuel and a fertilizer from 1 crop.

    Maybe bio-diesel production could work similar. Grow the grain, extract the oil for bio-diesel. The "meal" that is left over can be fed to animals or used directly to get methane and then fertilizer for more crops. This gets us 2 fuels, 1 animal food and a fertilizer.

  2. #2
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    3 things to get ideal conditions for methane production. The first is a temperature of 95 degrees. The second is to maintain a carbon/nitrogen ratio of 30:1 in the "organic matter" used to load the methane generator. Third is the dillution ratio in water of the organic matter.

    The above are all easily taken care of and with exception to temperature the other 2 parameters can vary quite a bit but its better to keep the C/N ratio at or above 30:1. Just FYI the temperature is important for 2 reason... lower the temp and less of the organics will convert into gases *AND* the percent of the gas that is actually methane will also be lower. Raise the temp above 95 and production slows until at 104 it stops completely.

    Thats how to make methane from organic matter now the hard part which is the design of an efficient methane generator that does all of the above. This I could use advice on. 4 major issues that I can think of right away are loading of a methane generator, prevention of sludge buildup, unloading the effluent and using the gas.

    Any design ideas for a generator? Thing is I am working on something that will produce alot of organic waste (not manure) and will have a small 2 car garage sized building to power and keep warm. If I can use the organics to save on an incredible electric bill by generating a useful gas from waste that would be awesome.

    Best design I can think of so far uses 55 gallon steel barrels welded together to form a long pipe. This would sit on something that allows it to be rotated so that sludge can be knocked free. At one end is the input and at the other is the output problems occur however when its rotated.

  3. #3
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    Did you see this sentence in the link you provided?

    "However, as to mass use, that seems doubtful. There is simply not enough of a supply of chicken manure to provide fuel for autos on a mass basis."

    Before embarking on designing and building something you should find out how much energy can be obtained in the form of methane from a given amount of organic material. Methane is often collected as a byproduct of treating sewage and you may be able to Google and find some numbers for the Methane produced from a given quantity waste.
    An open mind is a virtue...so long as all the common sense has not leaked out.

  4. #4
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    Hi smertrios

    There are many cities across the US & other countries that are already doing this They are putting wells into old land fills to get the methane gas out which power big engines & generators that are supplying thousands of homes with power from this, NewZealand was doing this 20 or more years ago

    I think by making a digester would work & the by product could be used for fertilizer or compressed into pellets for burning also some can be used for animal food
    Mactec54

  5. #5
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    Quote Originally Posted by mactec54 View Post
    ...I think by making a digester would work & the by product could be used for fertilizer or compressed into pellets for burning also some can be used for animal food
    Fertilizer yes but pellets for burning or animal food no. Animal food and burning requires carbohydrate and this is what the methane generating bacteria use for their food when they make methane. They gobble up the available carbohydrate and convert part of it into CO2 to get the energy they need for their existence; the other part gets converted to methane because they are living under anaerobic conditions and do not have oxygen available.
    An open mind is a virtue...so long as all the common sense has not leaked out.

  6. #6
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    Geof..I don't see any man like u here.. u have command on every topic..are u an engineer, researcher, CNC specialist, professor..... Who are u man

  7. #7
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    Just to make a couple of comments:
    "Maybe bio-diesel production could work similar. Grow the grain, extract the oil for bio-diesel." Grain crops can be used to make ethanol but not bio-diesel. Bio-diesel is normally made from oil producing plants.
    "Methane is often collected as a byproduct of treating sewage" Yes but if it is being considered for use as a fuel there is the problem of a very high acid content. When used in conjunction with a small turbine to produce electricity, these acids very quickly "eat" the turbine wheels.

    Khalid, yes you are right about Geoff as his knowledge seems to be spread across many fields.

  8. #8
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    Quote Originally Posted by Khalid View Post
    Geof..I don't see any man like u here.. u have command on every topic..are u an engineer, researcher, CNC specialist, professor..... Who are u man
    I have been criticized for bragging but what the h*ll it is not bragging if you can back it up. I completed a five year apprenticeship as a Fitter, Turner and Toolmaker in New Zealand in 1964 on my twenty first birthday actually. Then I took night school courses in Steam Engineering and Thermodynamics. I got interested in science and went to university for a few years completing the requirements for a major in Chemistry and a minor in Physics but then switched fields and finally earned an Honours Degree in Biochemistry. Then I did graduate work and earned a Doctorate in Biological Chemistry (now called Molecular Biology), did university research for a couple of years, taught college part time for four years then started my own business. The only one in your list that I have not been is an engineer.
    An open mind is a virtue...so long as all the common sense has not leaked out.

  9. #9
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    Hi Geof

    All the things that I said are being done/used Geof

    Organic Waste turned into Methane Gas= Mash one of the main things left after this process is Cellulose which is being used for Animal Food as the Animals break this down into Sugars=Energy for the Animal

    The mash is also turned into pellets for Burning

    After you have got the heat from Burning you get the Ash

    The Ash is then used for Fertilizer


    I think you need to do some more study on this subject before making comments that it can't be done
    Mactec54

  10. #10
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    Smertrios;

    I found this while Googling. It gives the energy equivalency for a variety of stuff that can go into a methane digester.

    http://www.mwk-biogas.com/DOCS/Sampl...Substrates.pdf


    mactec54;

    If you have some links I would like to see them. My understanding is that 'mash', which is obtained by partial digestion of corn starch and other starch containing grains to produce glucose, goes into ethanol fermentation. After the glucose has been used by the yeast to make ethanol a 'high protein mash' is obtained as a by-product and this can be fed to cattle or digested in a methane digester. What comes out of a methane digester has plenty of minerals and forms a good fertilizer for crops, but it has virtually no organic carbon in the form of cellulose or starches.
    An open mind is a virtue...so long as all the common sense has not leaked out.

  11. #11
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    geof;

    To me the graph was very interesting because of what it showed for wheat yields when compared to the chicken manure per ton. I know from reading the article on Harold Bate's methane car that he claims to be getting around 6 cubic feet per pound. That to me seemed great then I see that graph where the yellow bar for poultry is shown quite small in comparison to wheat! I guess its time to tell why that is interesting to me... I am raising superworms and they eat alot of wheat bran! The frass does not count as a manure does it?

  12. #12
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    Quote Originally Posted by Smertrios View Post
    geof;... I am raising superworms and they eat alot of wheat bran! The frass does not count as a manure does it?
    Snake food!!!!????

    I guess the frass does count as manure; after all the stuff that comes out of a cow after it has eaten grain is called manure so why should meal worms be any different.

    The suitability of any waste product for use in a methane digester depends on how much carbohydrate it contains, i.e. how much cellulose or starch; that is what the methane generating bacteria use as their food. I suspect that frass might be low on the scale because it contains chitin which is not particularly digestible by any bugs.

    I am really intrigued by what you a growing; many years ago, back in 1985, I was considering various possible business plans and one of them was growing meal worms to use as food for farmed salmon. I figured I could get bran which is (or was) almost a waste product, use the bran to grow meal worms and then feed the meal worms to the salmon which are a high value product.

    I met with several people who were involved in salmon farming and had been promised an interview with an investor who might have financed the project, but before the meeting took place this person had a heart attack. At about the same time I started to get involved in making equipment for people with a disability and my current busines grew out of that.
    An open mind is a virtue...so long as all the common sense has not leaked out.

  13. #13
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    In the Harold Bate article about using methane to power a car he say 1100 PSI to liquefy the methane. What I am reading from google searching says methane will not liquefy at room temperature no matter what amount of pressure is used *but* the CO2 will liquefy and then the methane will dissolve into the liquid CO2. The Harold Bate article says its "pure" methane but thats obviously not so.

  14. #14
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    6 cubic feet per pound of chicken manure across 30 days... thats 14.4 cubic inches per hour. I have had just over 1/2 pound of frass in a 2-liter bottle for 24 hours now and it has built up pressure but I am not getting anywhere near 14.4 cubic inches. I used aquarium water thinking that would eliminate any delay in gas generation but I may be expecting to much.

  15. #15
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    geof;

    Would you know about the efficiency of storing methane disolved in liquid CO2? Still very high pressure but I'm thinking that this must be how Harold Bate was getting "liquid methane". I am assuming a large quantity of methane will disolve into liquid CO2.

  16. #16
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    Quote Originally Posted by Smertrios View Post
    geof;

    Would you know about the efficiency of storing methane disolved in liquid CO2? Still very high pressure but I'm thinking that this must be how Harold Bate was getting "liquid methane". I am assuming a large quantity of methane will disolve into liquid CO2.
    I cannot give you a good answer; I also do not understand how he got 'liquid methane' at only 1100psi.

    You are correct that methane cannot be liquified no matter what the pressure at normal temperatures; it has to be cooled and kept at a low temperature but still under some pressure.

    Carbon dioxide can be liquified and at around 20 degrees C the pressure needed is about 1800psi.

    In other words Bates was not even at the pressure to liquefy CO2 so I do not know what he can have been getting.

    I cannot give a definite answer about methane dissolving into liquid CO2 but my feeling is that it would not be a very efficient method for storage.

    I Googled "methane solubility in liquid carbon dioxide" and did not get any hits with the quotes but with them removed there were a lot but non specifically dealing with methan dissolving into liquid CO2.

    I do not expect that methane will mix very well in liquid CO2 because the two molecules are very different. Methane is somewhat similar to gasoline (petrol) being composed of only carbon and hydrogen while CO2 is somewhat similar to water; in chemical terms methane is non-polar while CO2 is polar. You probably know that petrol does not mix very well with water and I think your 'large quantity' may be 'very small quantity'.

    The second problem I see is that when you try to extract the methane you are going to get it mixed with CO2.

    I suspect that if methane would dissolve efficiently in liquid CO2 it would already be in use for the transport of methane by ship; this is done on a large scale, Google 'LNG tankers' and if it could be done more efficiently using liquid CO2 I don't think the high pressure refigerated tanks would be used.
    An open mind is a virtue...so long as all the common sense has not leaked out.

  17. #17
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    IF you go looking up work done by the Chinese in the 1960's on Methane generation you can see that it does have it's uses but there is a demand limit as well as a having to deal with changing tanks and cleaning a tank out to re seed it and keep methane production going. There are generators out there that do run on methane and some cities are force seeding the bacteria into landfills as it does speed up decomp' of the land fill and produce a usable by product. Most systems that work worth a darn are buried as that helps with the heat issue to a degree (54°F below the frost line) so good luck and best wishes.

  18. #18
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    My 2 liter bottle test was semi-successful. It did generate methane but I put too much frass in the bottle and the small bubbles that would form on the frass would not pop and instead lifted the frass to the top and eventually out the tube I had in the top of the bottle. I emptied some out and refilled the remainder of the bottle with tap water and this was a mistake as the chemicals in tap water completely shut down the generator.

    I tried again using a 1 gallon milk jug but again I used too much frass and had a similar problem with the frass. This time I dumped out the bottle and just rinsed off the top before refilling with aquarium water... the small amount of tap water that got in the bottle seems to have been sufficient to kill off the bacteria =/

    The bubbling off the gallon jug with 1 pound of frass in it was sort of impressive. After 2-1/2 days it would release a bubble of gas about 2-3 times a second from a 3/16" rigid aquarium tube. A very tiny amount of gas but I keep thinking "its only 1 pound" and I have at least 200 pounds of frass in a 55 gallon trash can =P. If that rate of fermentation kept up for a month or more and was 200x faster it would run a heater full blast quite easily!

  19. #19
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    methane gas from manure

    I am interested in making methane gas as did Harold Bates and run an automobile on it.If you have any experience and know how I would appreciate advice and results you may have.

  20. #20
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    Smertrios

    This link may help with how they liquefy the methane gas

    http://www.acrion.com/LNG%20from%20LFG.htm

    Here is another good link

    http://extension.missouri.edu/public...b.aspx?P=G1881
    Mactec54

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