Try higher the acceleration parameter of the axes, because when cutting curves then the axes always have to accelerate and deccelerate and that could limit your cutting speed.
With a straight line it is accelerating up, going with programmed speed and deccelerating down. With a curve it is continous accelerations and deccelerations and if your axes acceleration is set low in the setup then the tool can not reach the target speed.
G0 is the rapid move and it is the fastest possible speed. The machine can move with that speed only if G0 is coded or if the F feedrate is set high than the maximum possible feedrate and G1, G2, G3 etc. is programmed with that feedrate.
In the UCCNC you can check the toolpath, the G0 lines are drawn with different color (red). And you can also check your g-code file. You can scroll the g-code view to the specific line and then check if it is a G0 or else. The UCCNC draws the selected line with different color on the toolpath view.